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NEET 2020 Chemistry : Chemical Kinetics and Nuclear Chemistry Quiz -2(21.06.2019)

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Question 1

Half-life period of a first order reaction is 1386 s. The specific rate constant of the reaction is

Question 2

Mechanism of a hypothetical reaction
is given below:
(i)
(ii)
(iii)
The overall order of the reaction will be:

Question 3

The rate constants k1 and k2 for two different reactions are 1016. e-2000/T and 1015. e-1000/T, respectively. The temperature at which k1= k2 iS

Question 4

The reaction of hydrogen and iodine monochloride is given as :
H2(g) + 2ICl(g) 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g), following mechanisms were proposed :
Mechanism A :
H2(g) + 2ICl(g) 2HCl(g) + I2(g)
Mechanism B :
H2(g) + ICl(g) HCl(g) + HI(g); slow
HI(g) + ICl(g) HCl(g) + I2(g); fast
Which of the above mechanism(s) is more appropriate with the given information about the reaction?

Question 5

The rate of a first-order reaction is 0.04 mol l‑1 s-1 at 10 seconds and 0.03 mol l-1 s-1 at 20 seconds after initiation of the reaction. The half-life period of the reaction is:

Question 6

For the reaction, N2 + 3H22NH3, if=2 x 10-4 mol L-1s-1, the value of would be

Question 7

Consider the reaction
N2(g) + 3H2(g) 2NH3(g)
The equality relationship between and is :

Question 8

The bromination of acetone plat occurs in acid solution is represented by this equation.
CH3COCH3(aq)+ Br2(aq) CH3COCH2Br(aq) + H+(aq) + Br-(aq)
These kinetic data were obtained for given reaction concentrations.

Initial concentrations, M
Initial rate,  Ms-1

 

Based on these data, the rate equation is

Question 9

In a zero order reaction for every 10 ° rise of temperature, the rate is doubled. If the temperature is increased from 10 °C to 100 °C, the rate of the reaction will become

Question 10

If 50% of a reaction occurs in 100 second and 75% of the reaction occurs in 200 second, the order of this reaction is :
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